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Cubic harmonic : ウィキペディア英語版
Cubic harmonic

In fields like computational chemistry and solid-state and condensed matter physics the so-called atomic orbitals, or spin-orbitals, as they appear in textbooks〔
〕〔
〕〔
〕 on quantum physics, are often partially replaced by cubic harmonics for a number of reasons.
==Introduction==
The l(l+1) hydrogen-like atomic orbitals with principal quantum number n and angular momentum quantum number l are often expressed as
:\psi_(\bold) = R_(r) Y_l^m(\theta,\varphi)
in which the R_(r) is the radial part of the wave function and Y_l^m(\theta,\varphi) is the angular dependent part. The Y_l^m(\theta,\varphi) are the spherical harmonics, which are solutions of the angular momentum operator. The spherical harmonics are representations of functions of the full rotation group SO(3)〔
〕 with rotational symmetry. In many fields of physics and chemistry these spherical harmonics are replaced by cubic harmonics because the rotational symmetry of the atom and its environment are distorted or because cubic harmonics offer computational benefits.

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